Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5223080 | Tetrahedron | 2010 | 13 Pages |
Abstract
The total synthesis and determination of the absolute configuration of (+)- and (−)-sundiversifolide have been achieved via intramolecular acylation and Wittig-lactonization as the key steps. The xanthanolide sesquiterpene lactones, 8-epi-xanthatin (1), dihydroxanthatin (2), and xanthatin (3) were also prepared, starting from a common intermediate derived from the synthesis of sundiversifolide.
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