Article ID Journal Published Year Pages File Type
5223124 Tetrahedron 2010 10 Pages PDF
Abstract

This paper describes the use of zamoranic acid in the first semisynthesis of the furolabdane (+)-angeloyl-gutierrezianolic acid methyl ester diterpenoid, which also establishes the absolute configuration of the natural product. Direct deconjugation of Δ7 in zamoranic acid and Bestmann methodology for the furan ring synthesis are the key steps.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry