| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223223 | Tetrahedron | 2010 | 9 Pages |
Abstract
α-Aryl-α-aminocarbonyloxime O-pentafluorobenzoates are found to be promising precursors for synthesis of 2,3-disubstituted indole derivatives catalyzed by PdCl2(MeCN)2 in the presence of MgO as a base. The reaction is supposed to proceed via intramolecular aromatic C–H amination of a vinyl nitrene–palladium intermediate.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
