| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223316 | Tetrahedron | 2010 | 7 Pages |
Abstract
The β-aryl–β-silyl and β,β-disilyl propionates have been synthesized from cinnamates and β-silyl acrylates by a regiospecific reductive C-silylation using Mg/silyl chloride/DMF system at room temperature. These reductive C-silylation conditions have also been applied to δ-aryl substituted dienoates wherein silylation took place at the δ-position leading to the synthesis of single regioisomeric allylsilanes with very high stereoselectivity.
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Physical Sciences and Engineering
Chemistry
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