| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223406 | Tetrahedron | 2010 | 4 Pages |
Abstract
Reactions of methylenecyclopropylcarbinols 1 with acetals 2 in the presence of Lewis acid Sc(OPf)3 produce the ring-closure products 3-oxabicyclo[3.1.0]hexane in moderate to high total yields along with the products in trans-configuration as the sole or major one. The plausible reaction mechanism has been discussed, which is based on the Prins-type reaction mechanism.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
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