| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223436 | Tetrahedron | 2009 | 4 Pages |
Abstract
The first asymmetric total synthesis of prianosin B (1) is described. Formation of the 16,17-dehydropyrroloiminoquinone skeleton from the pyrroloiminoquinone unit is a key step in this synthesis. Thus, the detosylation and dehydrogenation reactions of the pyrroloiminoquinone unit are caused by the presence of a catalytic amount of NaN3.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yasufumi Wada, Kouji Otani, Noriko Endo, Yu Harayama, Daigo Kamimura, Masako Yoshida, Hiromichi Fujioka, Yasuyuki Kita,