| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223588 | Tetrahedron | 2008 | 5 Pages |
Abstract
The radical mediated azidosulfonylation of various alkenes and alkynes that are able to undergo a rapid radical rearrangement is reported. For instance, treatment of 1,6-dienes or 1-en-6-ynes with benzenesulfonyl azide affords cyclic azidosulfones. High yields are observed when tertiary alkyl radicals are azidated in the last step of the cascade process. The azidosulfonylation of β-pinene involving ring opening of the bicyclic skeleton is also reported.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Nathalie Mantrand, Philippe Renaud,