| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223678 | Tetrahedron | 2010 | 6 Pages |
Abstract
Chiral bicyclo[3.3.0]octatrienes with excellent enantioselectivity were synthesized from the simple starting materials of α,β-unsaturated aldehyde and cyclopentadiene via one-pot operation, which consisted of a diphenylprolinol silyl ether-mediated ene-type reaction, intramolecular addition reaction of cyclopentadiene moiety with aldehyde and dehydration reaction.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![One-pot synthesis of chiral bicyclo[3.3.0]octatrienes using diphenylprolinol silyl ether-mediated ene-type reaction](/preview/png/5223678.png "First Page Preview: One-pot synthesis of chiral bicyclo[3.3.0]octatrienes using diphenylprolinol silyl ether-mediated ene-type reaction")
Authors
Hiroaki Gotoh, Hiroshi Ogino, Hayato Ishikawa, Yujiro Hayashi,