Article ID Journal Published Year Pages File Type
5223714 Tetrahedron 2008 5 Pages PDF
Abstract

Oligoethylene glycol chains containing 2-5 ethylene glycol units, and possessing a benzyl alcohol and a benzoic acid end groups, can be quantitatively obtained by intramolecular Cannizzaro reaction of the corresponding remote benzaldehyde end groups. The process is quite effective if a complex with an appropriate cation is formed to allow the two aldehyde groups to be spatially confined near enough each other for the intramolecular redox process.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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