Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5223757 | Tetrahedron | 2008 | 9 Pages |
Abstract
The palladium-catalyzed arylation of aryl bromides can be carried out in the presence of bidentate phosphines, such as dppm, dppe, dppf, and Xantphos under mild conditions. The experimental results and the DFT calculations fully support for this reaction a mechanism proceeding by an intermolecular proton abstraction.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sergio Pascual, Paula de Mendoza, Ataualpa A.C. Braga, Feliu Maseras, Antonio M. Echavarren,