Article ID Journal Published Year Pages File Type
5223763 Tetrahedron 2008 8 Pages PDF
Abstract

Air stable benzodiazepine containing palladacycles were synthesized by a C–H activation reaction and studied by mass spectrometry and X-ray crystallography. Catalytic C–H functionalizations of 1-methyl-5-phenyl-1H-1,4-benzodiazepin-2(3H)-one with diphenyliodonium hexafluorophosphate led to a mixture, which included the starting material and the expected product 1-methyl-5-(2′-biphenyl)-1H-1,4-benzodiazepin-2(3H)-one.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry