| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5223979 | Tetrahedron | 2010 | 5 Pages |
Abstract
The addition of the N-pronucleophiles to 2- or 3-nitro-2-alkenoates in the presence of base provided Michael addition products. In the case of 3-nitro compounds, reaction occurred via the formation of α-adducts and the subsequent elimination of nitrous acid to produce olefins with high Z stereoselectivity. 3-Phthalimido-2-nitrocinnamate adduct 8a was converted into 2,3-diamino ester 11a.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Elzbieta Lewandowska, Kinga Wichlacz, Adam J. Sobczak,