Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5223984 | Tetrahedron | 2010 | 4 Pages |
Abstract
Electron-deficient olefins like α,β-unsaturated ester, amide, and phosphonate reacted with iodonium cation species generated by the anodic oxidation of iodide anion in Et3N-5HF/CH3NO2 to form corresponding iodofluorinated compounds in good to moderate yields. The reaction proceeds at room temperature under air atmosphere and constant current conditions. The iodofluorinated products were shown to be useful fluorine-containing building blocks.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hirokatsu Nagura, Shunsuke Kuribayashi, Yutaka Ishiguro, Shinsuke Inagi, Toshio Fuchigami,