| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5224080 | Tetrahedron | 2008 | 4 Pages |
Abstract
Hexafluoroisopropanol (HFIP) is explored as an effective medium for the synthesis of 2,3-unsaturated glycosides through allylic rearrangement of 3,4,6-tri-O-acetyl glucal. This metal-free, exclusively solvent-promoted Ferrier glycosylation, affords products in good to excellent yields and with good α-selectivity.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kavita De, Julien Legros, Benoit Crousse, Danièle Bonnet-Delpon,