Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5224163 | Tetrahedron | 2009 | 8 Pages |
Abstract
An efficient protocol for the asymmetric synthesis of triacetyl-d-erythro-sphingosine and D-1-deoxyallonojirimycin has been developed starting from commercially available propargyl alcohol. The key steps involved Sharpless asymmetric epoxidation and Miyashita C2 selective endo-mode azide opening of the 2,3-epoxy alcohol.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
R. Sridhar, B. Srinivas, K. Rama Rao,