Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5224372 | Tetrahedron | 2008 | 7 Pages |
Abstract
Titanium-mediated cross-coupling of allenic alcohols with alkynes has been investigated. Divergent reaction pathways were discovered that provide either stereodefined 1,4-dienes or substituted cross-conjugated trienes. In short, allene substitution plays a critical role in the determination of reaction pathway.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Heidi L. Shimp, Alissa Hare, Martin McLaughlin, Glenn C. Micalizio,