| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5224482 | Tetrahedron | 2008 | 8 Pages |
Abstract
Ab initio MO calculations were carried out to investigate the Gibbs free energy of the conformational isomers of cyclohexanone derivatives. The genesis of the stabilization of the axial conformers in 2- and 3-alkyl cyclohexanones has been attributed to the attractive, five-membered CH/Ï(CO) hydrogen bond.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Osamu Takahashi, Katsuyoshi Yamasaki, Yuji Kohno, Youji Kurihara, Kazuyoshi Ueda, Yoji Umezawa, Hiroko Suezawa, Motohiro Nishio,