| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5224568 | Tetrahedron | 2008 | 9 Pages |
Abstract
Asymmetric oxidation of 1,2-diols, aminoalcohols, and aminoaldehydes in the presence of copper(II) triflate and (R,R)-Ph-BOX was accomplished by electrochemical method using Brâ as a mediator. This oxidation was applicable to kinetic resolution of racemic cis-cycloalkane-1,2-diols, aminoalcohols, and aminoaldehydes to afford optically active compounds with good to high enantioselectivity.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Daishirou Minato, Hitomi Arimoto, Yoko Nagasue, Yosuke Demizu, Osamu Onomura,