| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5224678 | Tetrahedron | 2009 | 10 Pages |
Abstract
Stable silylketenes, prepared by rhodium-catalysed decomposition of silyldiazoketones, undergo addition/cyclocondensation sequences with aminophenols and aminomalonate to give α-silylalkylbenzoxazoles and oxazoles, respectively. The silicon can be retained throughout functional group interconversions or can be removed by protodesilylation under acidic conditions as desired.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Stephen P. Marsden, James T. Steer, Barry S. Orlek,