Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5225037 | Tetrahedron | 2007 | 6 Pages |
Abstract
Two tripodal alcohols, viz., 1,1,1-tris(hydroxymethyl)ethane and α,α,α-tris(hydroxymethyl)toluene were converted by an efficient multi-step pathway involving azide formation into the corresponding tris(iminophosphorane) scaffolds bearing cyclopentyl (Cp) or phenyl groups on their phosphorus atoms, R-C(CH2-NPRâ²3)3 (R=Me or Ph, Râ²=Cp or Ph). The synthesis of some representative transition-metal complexes of Cu(I), Cu(II), Ni(II), and Pd(II) bearing these new tridentate ligands is also reported.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Laurence Beaufort, Lionel Delaude, Alfred F. Noels,