Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5225120 | Tetrahedron | 2008 | 14 Pages |
Abstract
Asymmetric allylation of aromatic aldehydes 1 with allyltrichlorosilane (2) can be catalyzed by new terpene-derived bipyridine N,Nâ²-dioxides 12-15 and an axially chiral biisoquinoline dioxide 17b with good enantioselectivities. Dioxides have been found to be more reactive catalysts than their monooxide counterparts.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Andrei V. Malkov, Mary-Margaret Westwater, Andrey Gutnov, Pedro RamÃrez-López, Frédéric Friscourt, Aneta KadlÄÃková, Jana HodaÄová, Zoran Rankovic, Martin Kotora, Pavel KoÄovský,