Article ID Journal Published Year Pages File Type
5225230 Tetrahedron 2007 5 Pages PDF
Abstract

A facile, convenient, efficient, and high yielding Rh(II)-catalyzed formation and rearrangement of trifluoroacetyl-containing sulfur ylides are reported. It is a Rh2(OAc)4-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylide intermediates generated from α-diazo compounds.

Graphical abstractDownload full-size imageA facile, convenient, efficient, and high yielding Rh(II)-catalyzed formation and rearrangement of trifluoroacetyl-containing sulfur ylides are reported.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, , , ,