Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5225357 | Tetrahedron | 2007 | 5 Pages |
Abstract
Two novel hydroxyl- and carboxyl-functionalized cubane-like photodimers from methyl 2-naphthoate have been successfully achieved under mild conditions. X-ray crystal structures confirm that the cubane-like structure is well retained in these two derivatives and the intermolecular OH⋯O hydrogen bonding plays an important role in crystal packing. It is of significance that the isolated racemic mixture can be subsequently resolved into two optically pure enantiomers by high-performance liquid chromatography.
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