Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5225418 | Tetrahedron | 2009 | 8 Pages |
Abstract
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
J. Robin Fulton, Lamin M. Kamara, Simon C. Morton, Gareth J. Rowlands,