| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5225433 | Tetrahedron | 2009 | 8 Pages |
Abstract
This paper describes the use of (â)-sclareol in the first synthesis of the spirolabdanolide (+)-leopersin D, which also establishes the absolute configuration of the product. The reversibility of conjugate addition/elimination of oxaspirolabdanolide formation is demonstrated.
Graphical abstractThe spirolabdanolide (+)-leopersin D has been synthesized from (â)-sclareol. The absolute configuration of the natural product has been established.Download full-size image
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
I.S. Marcos, L. Castañeda, P. Basabe, D. DÃez, J.G. Urones,