| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5225448 | Tetrahedron | 2009 | 5 Pages |
Abstract
The synthesis of the first C2 chiral phosphinine (phosphabenzene) and its pyrylium salt precursor is reported. The chiral phosphinine is derived from (+)-camphor, is a crystalline air-stable solid and is shown to effectively form complexes with metals. A preliminary result using the phosphinine as a ligand for asymmetric catalysis is reported and rationalized structurally.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
