| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5225462 | Tetrahedron | 2009 | 6 Pages |
Abstract
Asymmetric reduction of prochiral ketimines 1a-f with trichlorosilane can be catalyzed by the Lewis-basic formamides (S)-4a,b, derived from N-methyl valine, with â¤91% enantioselectivity and low catalyst loading (â¤5 mol %) at room temperature in toluene.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Andrei V. Malkov, Kvetoslava Vranková, Ralph C. Sigerson, Sigitas StonÄius, Pavel KoÄovský,