Article ID Journal Published Year Pages File Type
5225646 Tetrahedron 2006 7 Pages PDF
Abstract

The reactions of alkylidenepyrrolidine esters with isocyanates generally favour C-acylation, except in the case of benzyl isocyanate. Reactions with alkyl isocyanates are slow, and require forcing conditions. Reactions with isothiocyanates give exclusively the C-acylated products.

Graphical abstractDownload full-size imageThe title reactions give predominantly the C-acyl products rather than the previously-reported N-acyl products.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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