Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5225646 | Tetrahedron | 2006 | 7 Pages |
Abstract
The reactions of alkylidenepyrrolidine esters with isocyanates generally favour C-acylation, except in the case of benzyl isocyanate. Reactions with alkyl isocyanates are slow, and require forcing conditions. Reactions with isothiocyanates give exclusively the C-acylated products.
Graphical abstractDownload full-size imageThe title reactions give predominantly the C-acyl products rather than the previously-reported N-acyl products.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Christopher D. Davies, Mark C. Elliott, John L. Wood,