| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5225846 | Tetrahedron | 2010 | 5 Pages |
Abstract
The palladium-catalyzed semi-hydrogenation of alkynes to trans- or cis-alkenes employing HSiEt3 as the reductant is developed. The CuSO4 played a significant role for the trans/cis stereoselectivity. The labeling study revealed that the two olefinic hydrogen atoms came from HSiEt3 and H2O, respectively.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Fang Luo, Changduo Pan, Wenhui Wang, Zhishi Ye, Jiang Cheng,