| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5226236 | Tetrahedron | 2009 | 5 Pages |
Abstract
(E)-O-Arylsulfonyl-N-(2-nitroalk-2-enyl)hydroxylamines were easily obtained in good yields starting from (E)-nitro allylic alcohols, the crucial step being an inorganic base-catalyzed decarboxylative rearrangement of proposed labile unsaturated carbamates. A possible mechanism for the outcome of the reaction, characterized by the unusual retention of the sulfonyloxy group, is proposed.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Stefania Fioravanti, Lucio Pellacani, Paolo A. Tardella,