Article ID Journal Published Year Pages File Type
5226389 Tetrahedron 2009 7 Pages PDF
Abstract

The enantioselective hydrophosphonylation reaction of diisopropyl phosphite with aldimine furnished α-amino phosphonates with high enantioselectivities by means of a chiral phosphoric acid. DFT calculation of the effect of 3,3′-substituents of the phosphoric acid revealed the reason for the high enantioselectivities.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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Chiral Brønsted acid-catalyzed hydrophosphonylation of imines-DFT study on the effect of substituents of phosphoric acid
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