| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5226395 | Tetrahedron | 2009 | 12 Pages |
Abstract
A rhodium(I)-xylyl-BINAP catalyzed asymmetric [2+2+2] cycloaddition of achiral conjugated aryl ynamides with various diynes is described here. This asymmetric cycloaddition provides a series of structurally interesting chiral N,O-biaryls with excellent enantioselectivity along with a modest diastereoselectivity with respect to both C–C and C–N axial chirality.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
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