| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5226407 | Tetrahedron | 2009 | 8 Pages |
Abstract
A variety of β-S-substituted aldehydes undergo efficient and regioselective rhodium catalyzed hydroacylation reactions with 1,3-disubstituted and 1,1,3-trisubstituted allenes, to deliver β,γ-unsaturated ketone products. Regioselectivites are controlled primarily by steric factors. The reactions are catalyzed by the complex [Rh(dppe)]ClO4.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Helen E. Randell-Sly, James D. Osborne, Robert L. Woodward, Gordon S. Currie, Michael C. Willis,