Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5226611 | Tetrahedron | 2006 | 5 Pages |
Abstract
The total synthesis of two novel l-ido and l-altro configured 6-chloro-1,5,6-trideoxyiminohexitols featuring a highly diastereoselective Pd(II)/CuCl2-catalysed chlorocyclisation of sugar-derived aminoalkenitols has been accomplished. The requisite substrates were, in turn, prepared from chiral pool materials starting from the cheap and commercially available methyl-α-d-gluco- and methyl-α-d-galactopyranoside.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Peter Szolcsányi, Tibor Gracza,