Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5226966 | Tetrahedron | 2007 | 7 Pages |
Abstract
The one-pot construction of perhydrophenanthrene from an acyclic substrate was achieved via a sequential pericyclic reaction, which involved the in situ generation of ene-diallene species due to Myers' propargyl alcohol-allene transformation. The resulting perhydrophenanthrene derivative could be successfully converted into (±)-estrone.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hirohumi Hakuba, Shinji Kitagaki, Chisato Mukai,