| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5226978 | Tetrahedron | 2007 | 5 Pages |
Abstract
Treatment of α,β-unsaturated ketones and fluoroalkyl halides with Et2Zn in the presence of RhCl(PPh3)3 gave novel reductive fluoroalkylation products at the α-position of α,β-unsaturated ketones in moderate to good yields. The rhodium hydride complex derived from Et2Zn and Rh catalyst seems to have played an important role in this reaction.
Graphical abstract
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kazuyuki Sato, Yoshitaka Ishida, Eriko Murata, Yumiko Oida, Yasumitsu Mori, Miho Okawa, Kayoko Iwase, Atsushi Tarui, Masaaki Omote, Itsumaro Kumadaki, Akira Ando,