Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5227027 | Tetrahedron | 2009 | 5 Pages |
Abstract
For the first time, substituents to the 3-position of 2-oxosparteine have been introduced. The synthesis of 3-phenylthiolupanine, 3,3-di(phenylthio)lupanine, 3-dehydrolupanine, 3-bromodehydro-lupanine and 2-thiono-3-dehydrosparteine has been described. The stereochemistry of these compounds has been determined and by NMR spectroscopy and X-ray crystallography.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry