Article ID Journal Published Year Pages File Type
5227041 Tetrahedron 2009 8 Pages PDF
Abstract

A highly stereoselective asymmetric total synthesis of marine polypropionate (−)-baconipyrone C has been achieved. Utilization of desymmetrization technique to create five stereogenic centres, Sharpless epoxidation, Gilman's reaction and resolution of methyl group using enzyme PS-C is the highlight of the synthesis.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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