| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5227058 | Tetrahedron | 2006 | 10 Pages |
Abstract
A nickel catalyst prepared from Ni(cod)2 and PMe3 is found to effect arylcyanation reaction of alkynes, namely, cleavage of a C–CN bond of an aryl cyanide followed by addition of each fragment across an alkyne. A wide range of functional groups in aryl cyanides tolerated the catalysis, giving variously functionalized β-arylalkenenitriles stereoselectively.
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Physical Sciences and Engineering
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Organic Chemistry
