| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5227099 | Tetrahedron | 2009 | 8 Pages |
Abstract
Electrochemical fluoro-selenenylation of electron-deficient olefins like α,β-unsaturated ester, carboxylic acid, amide, and phosphonate was successfully carried out by the anodic oxidation of diphenyl diselenide in the presence of olefins in Et3N·5HF/CH3NO2. The anodically generated benzeneselenenyl fluoride [PhSeF] equivalent was stable in the electrolytic solution, which resulted in the efficient fluoro-selenenylation. The fluoro-selenenylation products were shown to be potential useful fluoro-building blocks.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hirokatsu Nagura, Shinsuke Inagi, Toshio Fuchigami,