| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5227345 | Tetrahedron | 2007 | 8 Pages |
Abstract
Chemical synthesis of two trisaccharides related to the saponin isolated from Centratherum anthelminticum is reported. Stereoselective, high-yielding glycosylation strategies were developed using H2SO4 immobilized on silica for activation of trichloroacetimidate donors, or in conjunction with N-iodosuccinimide for activation of a thioglycoside. A late stage TEMPO-mediated oxidation was performed for the formation of the required uronic acid moiety.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Santanu Mandal, Balaram Mukhopadhyay,