Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5227391 | Tetrahedron | 2006 | 19 Pages |
Abstract
Total synthesis of (â)-actinobolin starting from d-glucose is described. Stereocontrolled three-component coupling reactions of a cyclohexenone derived from d-glucose by way of Ferrier's carbocyclization, with vinyl cuprate and 2-alkoxypropanal effectively constructed the carbon framework of 3. The formal synthesis of (+)-actinobolin starting from d-glucose was also accomplished.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Satoshi Imuta, Hiroki Tanimoto, Miho K. Momose, Noritaka Chida,