Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5227793 | Tetrahedron | 2008 | 7 Pages |
Abstract
Regio- and stereocontrolled alkoxy mercuration of α,β-unsaturated esters allows direct access to 1,3-syn diols in good yields. Demercuration of adducts leads to 1,3 skipped dihydroxy esters, alcohols, and α-halo esters. The deprotection of acetonide with Amberlyst 15 on 1,3-syn-dihydroxy esters gives the corresponding δ-lactones.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Carlo Bonini, Maria Campaniello, Lucia Chiummiento, Valeria Videtta,