Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5227795 | Tetrahedron | 2008 | 9 Pages |
Abstract
We describe a novel synthesis of various carbamate- and urea-linked disaccharides stereospecifically using sugar carboxylic acids and sugar alcohols or sugar amines by the modified Curtius rearrangement. In this reaction, the reactivity of each hydroxyl group in glucose as an acceptor has been disclosed. Furthermore, we applied this method to the synthesis of carbamate-linked oligosaccharides including a dendritic molecule.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Daisuke Sawada, Shinya Sasayama, Hideyo Takahashi, Shiro Ikegami,