| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5227838 | Tetrahedron | 2007 | 5 Pages |
Abstract
The Diels-Alder reactions of 5-nitro[2.2]paracyclophanepyran-6-one with 1,3-butadienes and 1,2-dihydro-3-vinyl-naphthalene were examined under thermal and high-pressure conditions. The cycloadditions with 1,3-butadienes occurred in good yield and anti-exo diastereoselectively only under high-pressure conditions; the one with 1,2-dihydro-3-vinyl-naphthalene afforded comparable yields of mixtures of anti/syn adducts under normal and high-pressure conditions. A structural analysis of the reaction products by 1H and 13CÂ NMR spectroscopy is presented.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
![High pressure and thermal Diels-Alder reactions of 5-nitro[2.2]paracyclophanepyran-6-one](/preview/png/5227838.png "First Page Preview: High pressure and thermal Diels-Alder reactions of 5-nitro[2.2]paracyclophanepyran-6-one")
Authors
Lucio Minuti, Assunta Marrocchi, Selvaggia Landi, Mirko Seri, Eszter Gacs-Baitz,