| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5227969 | Tetrahedron | 2005 | 7 Pages |
Abstract
The development of a high-load, soluble oligomeric sulfonyl azide using ROM polymerization is reported. The utility in diazo transfer reactions with active methylene compounds is demonstrated using an efficient protocol, with most reactions showing completion in 30 minutes. The sulfonamide byproduct, being insoluble in the reaction solvent, can be completely removed by simple filtration through a silica gel SPE cartridge.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Andrew M. Harned, W. Matthew Sherrill, Daniel L. Flynn, Paul R. Hanson,