Copper (I) 1,3-R2-3,4,5,6-tetrahydropyrimidin-2-ylidenes (R=mesityl, 2-propyl): synthesis, X-ray structures, immobilization and catalytic activity

Article ID	Journal	Published Year	Pages	File Type
5227976	Tetrahedron	2005	8 Pages	PDF

Abstract

Novel Cu (I) N-heterocylic carbene complexes have been synthesized from CuX (X=Cl, Br) and 1,3-R2-3,4,5,6-tetrahydropyrimidin-2-ylidenes (R=2-Pr, mesityl). These were used in CO hydrosilylation and CO hydrocyanation reactions as well as in the ATRP of methyl methacrylate.

Keywords

Hydrosilylation Cyanosilylation N-Heterocyclic carbenes Copper atom-transfer radical polymerization Homogeneous catalysis Heterogeneous catalysis

Related Topics

Physical Sciences and Engineering Chemistry Organic Chemistry

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Copper (I) 1,3-R2-3,4,5,6-tetrahydropyrimidin-2-ylidenes (R=mesityl, 2-propyl): synthesis, X-ray structures, immobilization and catalytic activity

Authors

Bhasker Bantu, Dongren Wang, Klaus Wurst, Michael R. Buchmeiser,