Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5228171 | Tetrahedron | 2008 | 5 Pages |
Abstract
The preparation of 1,1-disubstituted and monosubstituted cyclopropanes from corresponding 2,2-disubstituted and 2-monosubstituted 1,3-dihalopropanes, respectively, with SmI2 in THF was efficiently carried out. The reaction mechanism was proposed to proceed in a radical 3-exo-tet manner based on Baldwin's rule.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Tsuyoshi Ohkita, Yuhsuke Tsuchiya, Hideo Togo,