Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5228213 | Tetrahedron | 2007 | 6 Pages |
Abstract
On the basis of the concept of partial template, triangular trisaloph ligands 2a and 2b reacted with excess ZnII to give heptanuclear Zn clusters with a similar geometry. The Zn complex of 2c, which was difficult to be prepared according to a previous procedure, was synthesized in high yield in a one-pot fashion. Various multi-nuclear complexes of 2a with Mn, Co, Ni, and Cu were also produced, although the trinuclear MnII and CoII complexes were smoothly oxidized to the MnIII and CoIII complexes.
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