Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5228404 | Tetrahedron | 2008 | 7 Pages |
Abstract
Two new synthetic approaches, involving substrate directed aza-Claisen rearrangements and aza-Claisen rearrangements mediated by chiral Pd(II) catalysts, have been developed for the stereoselective synthesis of (2R,3S)-2-amino-3,4-dihydroxybutyric acid, a dihydroxylated α-amino acid from the edible mushroom, Lyophyllum ulmarium and its (2S,3S)-unnatural diastereomer.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Michael D. Swift, Andrew Sutherland,